The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Halogen oxides / Cl oxides / ClO / GillespieDonovan(1976)_293K_277.2-285.2nm

DATAFILE: ClO_GillespieDonovan(1976)_293K_277.2-285.2nm.txt
NAME: chlorine monoxide
FORMULA: ClO
AUTHOR(YEAR): GillespieDonovan(1976)
T: 293K
λ: 277.2-285.2nm
BIBLIOGRAPHY: H.M. Gillespie and R.J. Donovan, "Reaction of O(2 1D) atoms with chlorofluoromethanes: formation of ClO", Chem. Phys. Lett. 37, 468-470 (1976); DOI: 10.1016/0009-2614(76)85015-4
COMMENTS: The reaction of O(1D2) atoms with CF3CI, CF2Cl2 and CFCl3 has been investigated by flash photolysis with time-resolved absorption spectroscopy

Absorption cross sections for the (12-0) to (9-0) band heads were measured relative to the continuum value 5.20×10-18 cm2 molecule-1 at 257.7 nm of

M.A.A. Clyne and J.J.Coxon, Trans. Faraday Soc. 62, 1175- (1966)

The continuum value was revised later to 4.86×10-18 cm2 molecule-1 by

M.A.A. Clyne and J.A. Coxon, "Kinetic studies of oxy-halogen radical systems, Proc. Roy. Soc. London A 303, 207-231 (1968)

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